It is possible to be placed on one list and not the other. I have first-hand knowledge of a person whom was barred from working with Vulnerable Adults as a result of a concern raised by an employer and a subsequent DBS enquiry. However, they have not been placed on the Children's Barred List, and currently are working in a profession involving children.
I know only that the employer referral was made due to a incident of alleged "neglect", and the DBS decided to bar the person in question. It does seem quite strange that they would bar them from working with Vulnerable Adults and not children, but this is absolutely categorically the case and even the DBS certificate shows this, so... it's possible.
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